Influence of the medium upon the rate of complexing of In3+ and Ga3+
Identifieur interne : 000327 ( Main/Exploration ); précédent : 000326; suivant : 000328Influence of the medium upon the rate of complexing of In3+ and Ga3+
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Abstract
The rate and the rate constant of the process of complexing of In3+ and Ga3+ were evaluated in media containing hydrochloric acid, sulfuric acid or nitric acid and different organic solvents. It was established that the rate of the process is maximum in aqueous-acid environments (without presence of organic additions), in almost all investigated cases in the first minutes of the reaction.
DOI: 10.1007/BF00811544
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<record><TEI><teiHeader><fileDesc><titleStmt><title>Influence of the medium upon the rate of complexing of In3+ and Ga3+</title><author><name>M. Panaiotova</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia, Bulgaria</mods:affiliation><country xml:lang="fr">Bulgarie</country><wicri:regionArea>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia</wicri:regionArea><placeName><settlement type="city">Sofia</settlement><region nuts="2">Sofia-ville (oblast)</region></placeName></affiliation></author><author><name>R. Takeva</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia, Bulgaria</mods:affiliation><country xml:lang="fr">Bulgarie</country><wicri:regionArea>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia</wicri:regionArea><placeName><settlement type="city">Sofia</settlement><region nuts="2">Sofia-ville (oblast)</region></placeName></affiliation></author><author><name>M. Parlapanski</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia, Bulgaria</mods:affiliation><country xml:lang="fr">Bulgarie</country><wicri:regionArea>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia</wicri:regionArea><placeName><settlement type="city">Sofia</settlement><region nuts="2">Sofia-ville (oblast)</region></placeName></affiliation></author><author><name>L. Shishkova</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia, Bulgaria</mods:affiliation><country xml:lang="fr">Bulgarie</country><wicri:regionArea>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia</wicri:regionArea><placeName><settlement type="city">Sofia</settlement><region nuts="2">Sofia-ville (oblast)</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:706_1992_Article_BF00811544.pdf</idno><date when="1992">1992</date><idno type="doi">10.1007/BF00811544</idno><idno type="wicri:Area/Main/Corpus">000497</idno><idno type="wicri:Area/Main/Curation">000497</idno><idno type="wicri:Area/Main/Exploration">000327</idno></publicationStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Complexing</term><term>Gallium</term><term>Indium</term><term>Rate constant</term><term>Reaction rate</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">The rate and the rate constant of the process of complexing of In3+ and Ga3+ were evaluated in media containing hydrochloric acid, sulfuric acid or nitric acid and different organic solvents. It was established that the rate of the process is maximum in aqueous-acid environments (without presence of organic additions), in almost all investigated cases in the first minutes of the reaction.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="56efed936a11110736f248532be84151337fa576"><titleInfo lang="eng"><title>Influence of the medium upon the rate of complexing of In3+ and Ga3+</title></titleInfo><titleInfo lang="ger"><title>Einfluß des Reaktionsmediums auf die Komplexierungsgeschwindigkeit von In3+ und Ga3+</title></titleInfo><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Panaiotova</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia, Bulgaria</affiliation></name><name type="personal"><namePart type="given">R.</namePart><namePart type="family">Takeva</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia, Bulgaria</affiliation></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Parlapanski</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia, Bulgaria</affiliation></name><name type="personal"><namePart type="given">L.</namePart><namePart type="family">Shishkova</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Department of Chemistry, University of Mining and Geology, 1156 (Darvenitza), Sofia, Bulgaria</affiliation></name><typeOfResource>text</typeOfResource><genre>Anorganische Und Physikalische Chemie</genre><genre>Original Paper</genre><originInfo><publisher>Springer-Verlag, Vienna</publisher><dateCreated encoding="w3cdtf">1991-08-06</dateCreated><dateCaptured encoding="w3cdtf">1991-10-22</dateCaptured><dateValid encoding="w3cdtf">2004-11-29</dateValid><copyrightDate encoding="w3cdtf">1992</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">The rate and the rate constant of the process of complexing of In3+ and Ga3+ were evaluated in media containing hydrochloric acid, sulfuric acid or nitric acid and different organic solvents. It was established that the rate of the process is maximum in aqueous-acid environments (without presence of organic additions), in almost all investigated cases in the first minutes of the reaction.</abstract><abstract lang="ger">Es wurden die Komplexierungsgeschwindigkeiten von In3+ und Ga3+ in Lösungsmittelsystemen mit Salzsäure, Schwefelsäure oder Salpetersäure und verschiedenen organischen Lösungsmitteln gemessen. Dabei konnte gezeigt werden, daß die Geschwindigkeit in wäßrig-saurem Medium (ohne Zusätzen von organischen Verbindungen) und dann fast immer in den ersten Minuten der Reaktion am größten ist.</abstract><subject lang="eng"><genre>Keywords</genre><topic>Reaction rate</topic><topic>Rate constant</topic><topic>Complexing</topic><topic>Gallium</topic><topic>Indium</topic></subject><relatedItem type="series"><titleInfo type="abbreviated"><title>Monatsh Chem</title></titleInfo><titleInfo><title>Monatshefte für Chemie / Chemical Monthly</title><partNumber>Year: 1992</partNumber><partNumber>Volume: 123</partNumber><partNumber>Number: 10</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1992-10-01</dateIssued><copyrightDate encoding="w3cdtf">1992</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Chemistry/Food Science, general</topic><topic>Analytical Chemistry</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><topic>Physical Chemistry</topic><topic>Theoretical and Computational Chemistry</topic></subject><identifier type="issn">0026-9247</identifier><identifier type="issn">Electronic: 1434-4475</identifier><identifier type="matrixNumber">706</identifier><identifier type="local">IssueArticleCount: 10</identifier><recordInfo><recordOrigin>Springer-Verlag, 1992</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF00811544</identifier><identifier type="matrixNumber">Art5</identifier><identifier type="local">BF00811544</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>891</start><end>897</end></extent></part><recordInfo><recordOrigin>Springer-Verlag, 1992</recordOrigin><recordIdentifier>706_1992_Article_BF00811544.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
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